Natalie Portman and Robert Pattinson both attended the post Vanity Fair Oscar Party last night and Eonline scoops that Portman set her eyes on the “Twilight” hunk all night.

“[Portman] seemed really into him, and went right up to say hello once she spotted him,” said an insider who saw the two chatting at the event.

Why was the Oscar presenter jittery? Before the party, Rob told Eonline, “I was so nervous [about the Oscars]” the cute Brit told us, sexy accent ‘n’ all. To calm his nerves, he took to whiskey and Natalie Portman.

Eonline reports:

Robert, who flew solo, shy and rather lonely most of the glittering night, found a fan in the gorgeous Nat. Ms. P, who also had a little whatever with Ryan Gosling recently, was pretty and piranha-like in fuchsia.

The two totally flirted it up outside on the patio, and Rob started to feel right at home in his newly found Hollywood lifestyle.

N.P. was batting those beautiful eyelashes at Pattinson, and he seemed to be enjoying every minute of it. And there were a lot of minutes. I think Ms. P’s used to getting what she wants, as she dominated R.P.’s attentions most of the evening.

But fear not, ladies (and gents, too), it looks like Robalie’s just in the crush stage ’cause Mr. P was seen leaving sans Portman at the end of the night.

You think they’d make a good couple?

It seems Natalie Portman wasn’t a good enough reason to stick to Hollywood for a few more days. Just a day after the Academy Awards, Robert Pattinson left Los Angeles today (Feb. 23) and was seen arriving at LAX airport for a departing flight. Check out more pictures of Spank Ransom below…